Reaction Mechanism of 2-(Trimethylsilylmethyl)pyridine with Benzonitrile
نویسندگان
چکیده
منابع مشابه
2-(2-Hydroxybenzylideneamino)benzonitrile
The mol-ecule of the title compound, C(14)H(10)N(2)O, displays a trans configuration with respect to the C=N double bond. The mol-ecule is roughly planar; the two aromatic rings make a dihedral angle of 9.3 (3)°. Such a planar conformation is induced by the strong intra-molecular O-H⋯N hydrogen bond between the imine and hydroxyl groups.
متن کامل3-(2-Hydroxybenzylideneamino)benzonitrile
In the title mol-ecule, C(14)H(10)N(2)O, an intra-molecular O-H⋯N hydrogen bond contributes to the essential coplanarity of the two benzene rings, which form a dihedral angle of 6.04 (18)°.
متن کامل4-(2-Hydroxybenzylideneamino)benzonitrile
The mol-ecule of the title compound, C(14)H(10)N(2)O, is nearly planar. There is a strong intra-molecular O-H⋯N hydrogen bond between the imine and hydr-oxy groups. The configuration with respect to the C=N double bond is anti (1E).
متن کامل2-(4-Methylphenyl)benzonitrile
In the title compound, C(14)H(11)N, the dihedral angle between the mean planes of the two benzene rings is 44.6 (7)°. The crystal packing is stabilized by weak inter-molecular π-π stacking inter-actions, the centroid-centroid distances being 3.8172 (12) and 3.9349 (12) Å.
متن کامل2-[(E)-(Dimethylamino)methyleneamino]benzonitrile
In the title compound, C(10)H(11)N(3), the amidine unit, including the two methyl substituents, is virtually planar [maximum deviation = 0.016 (5) Å]. The plane of the benzene ring forms a dihedral angle of 46.5 (3)° with the amidine group.
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1983
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.56.1241